Title: Water co-catalysis in aerobic olefin epoxidation mediated by ruthenium oxo complexes

Authors (6): Q. Cao, M. Diefenbach, C. Maguire, V. Krewald, M. J. Muldoon, U. Hintermair

Themes: Circular Economy (2024)

DOI: 10.1039/d3sc05516g

Citations: 0

Pub type: journal-article

Publisher: Royal Society of Chemistry (RSC)


License: [{"start"=>{"date-parts"=>[[2024, 2, 7]], "date-time"=>"2024-02-07T00:00:00Z", "timestamp"=>1707264000000}, "content-version"=>"vor", "delay-in-days"=>37, "URL"=>"http://creativecommons.org/licenses/by/3.0/"}]

Publication date(s): 2024 (online)


Volume: Issue:

Journal: Chemical Science

Link: [{"URL"=>"http://pubs.rsc.org/en/content/articlepdf/2024/SC/D3SC05516G", "content-type"=>"unspecified", "content-version"=>"vor", "intended-application"=>"similarity-checking"}]

URL: http://dx.doi.org/10.1039/d3sc05516g

A versatile Ru-porphyrin catalyst system was developed for the mild and selective aerobic epoxidation of alkenes in which water was shown to play a key role as corroborated by detailed mechanistic studies.

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