Title: A highly active, thermally robust iron(iii)/potassium(i) heterodinuclear catalyst for bio-derived epoxide/anhydride ring-opening copolymerizations

Authors (5): W. T. Diment, G. Rosetto, N. Ezaz-Nikpay, R. W. F. .Kerr, C. K. Williams

Themes: Circular Economy (2023)

DOI: 10.1039/d2gc04580j

Citations: 13

Pub type: journal-article

Publisher: Royal Society of Chemistry (RSC)

Issue: 6

License: [{"start"=>{"date-parts"=>[[2023, 2, 27]], "date-time"=>"2023-02-27T00:00:00Z", "timestamp"=>1677456000000}, "content-version"=>"vor", "delay-in-days"=>57, "URL"=>"http://creativecommons.org/licenses/by-nc/3.0/"}]

Publication date(s): 2023/03/20 (print) 2023 (online)

Pages: 2262-2267

Volume: 25 Issue: 6

Journal: Green Chemistry

Link: [{"URL"=>"http://pubs.rsc.org/en/content/articlepdf/2023/GC/D2GC04580J", "content-type"=>"unspecified", "content-version"=>"vor", "intended-application"=>"similarity-checking"}]

URL: http://dx.doi.org/10.1039/d2gc04580j

A novel heterodinuclear Fe(iii)/K(i) catalyst is reported for the ring-opening copolymerization of epoxides and anhydrides, achieving turnover frequencies of up to 4800 h−1. It also shows activity for a broad range of bio-derived monomers.

Name Description Publised
CCDC 2207317: Experimental Crystal Structure Determination Wilfred T. Diment, Gloria Rosetto, Noura Ezaz-Nikpay, Ryan W. F. Kerr, C... 2023
CCDC 2207318: Experimental Crystal Structure Determination Wilfred T. Diment, Gloria Rosetto, Noura Ezaz-Nikpay, Ryan W. F. Kerr, C... 2023


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