Title: Controlled monodefluorination and alkylation of C(sp3)–F bonds by lanthanide photocatalysts: importance of metal–ligand cooperativity

Authors (9): A. E. Kynman, L. K. Elghanayan, A. N. Desnoyer, Y. Yang, L. Sévery, A. Di Giuseppe, T. D. Tilley, L. Maron, P. L. Arnold

Themes: Design (2022)

DOI: 10.1039/d2sc04192h

Citations: 14

Pub type: journal-article

Publisher: Royal Society of Chemistry (RSC)

Issue: 47

License: [{"start"=>{"date-parts"=>[[2022, 11, 8]], "date-time"=>"2022-11-08T00:00:00Z", "timestamp"=>1667865600000}, "content-version"=>"vor", "delay-in-days"=>311, "URL"=>"http://creativecommons.org/licenses/by-nc/3.0/"}]

Publication date(s): 2022/12/07 (print) 2022 (online)

Pages: 14090-14100

Volume: 13 Issue: 47

Journal: Chemical Science

Link: [{"URL"=>"http://pubs.rsc.org/en/content/articlepdf/2022/SC/D2SC04192H", "content-type"=>"application/pdf", "content-version"=>"vor", "intended-application"=>"syndication"}, {"URL"=>"http://pubs.rsc.org/en/content/articlepdf/2022/SC/D2SC04192H", "content-type"=>"unspecified", "content-version"=>"vor", "intended-application"=>"similarity-checking"}]

URL: http://dx.doi.org/10.1039/d2sc04192h

The controlled functionalization of a single fluorine in a CF3 group is difficult and rare. Photochemical C–F bond functionalization is achieved using catalysts made from a range of earth-abundant lanthanides by using a ligand that enables M–L cooperativity.

Name Description Publised
Supporting Information for Controlled Monodefluorination and Alkylation of C(sp3)-F Bonds by Lanthanide Photocatalysts: Importance of Metal-Ligand Cooperativity Supl. data to article... 2022
Crystal structure data Crystal structure data... 2022
CCDC 2121204: Experimental Crystal Structure Determination Amy E. Kynman, Luca K. Elghanayan, Addison N. Desnoyer, Yan Yang, Lauren... 2022
CCDC 2121205: Experimental Crystal Structure Determination Amy E. Kynman, Luca K. Elghanayan, Addison N. Desnoyer, Yan Yang, Lauren... 2022
CCDC 2121206: Experimental Crystal Structure Determination Amy E. Kynman, Luca K. Elghanayan, Addison N. Desnoyer, Yan Yang, Lauren... 2022
CCDC 2121207: Experimental Crystal Structure Determination Amy E. Kynman, Luca K. Elghanayan, Addison N. Desnoyer, Yan Yang, Lauren... 2022
CCDC 2121208: Experimental Crystal Structure Determination Amy E. Kynman, Luca K. Elghanayan, Addison N. Desnoyer, Yan Yang, Lauren... 2022
CCDC 2121209: Experimental Crystal Structure Determination Amy E. Kynman, Luca K. Elghanayan, Addison N. Desnoyer, Yan Yang, Lauren... 2022
CCDC 2121210: Experimental Crystal Structure Determination Amy E. Kynman, Luca K. Elghanayan, Addison N. Desnoyer, Yan Yang, Lauren... 2022
CCDC 2121211: Experimental Crystal Structure Determination Amy E. Kynman, Luca K. Elghanayan, Addison N. Desnoyer, Yan Yang, Lauren... 2022
CCDC 2121212: Experimental Crystal Structure Determination Amy E. Kynman, Luca K. Elghanayan, Addison N. Desnoyer, Yan Yang, Lauren... 2022
CCDC 2121213: Experimental Crystal Structure Determination Amy E. Kynman, Luca K. Elghanayan, Addison N. Desnoyer, Yan Yang, Lauren... 2022
CCDC 2121214: Experimental Crystal Structure Determination Amy E. Kynman, Luca K. Elghanayan, Addison N. Desnoyer, Yan Yang, Lauren... 2022
CCDC 2121215: Experimental Crystal Structure Determination Amy E. Kynman, Luca K. Elghanayan, Addison N. Desnoyer, Yan Yang, Lauren... 2022
CCDC 2217133: Experimental Crystal Structure Determination Amy E. Kynman, Luca K. Elghanayan, Addison N. Desnoyer, Yan Yang, Lauren... 2022


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