Title: Reactions of a diborylstannylene with CO2 and N2O: diboration of carbon dioxide by a main group bis(boryl) complex

Authors (6): A. V. Protchenko, M. ÁN. Fuentes, J. Hicks, C. McManus, R. Tirfoin, S. Aldridge

Themes: Transformations (2021)

DOI: 10.1039/d1dt01216a

Citations: 8

Pub type: journal-article

Publisher: Royal Society of Chemistry (RSC)

Issue: 26

License: [{"start"=>{"date-parts"=>[[2022, 4, 27]], "date-time"=>"2022-04-27T00:00:00Z", "timestamp"=>1651017600000}, "content-version"=>"am", "delay-in-days"=>481, "URL"=>"http://rsc.li/journals-terms-of-use"}]

Publication date(s): 2021/07/06 (print) 2021 (online)

Pages: 9059-9067

Volume: 50 Issue: 26

Journal: Dalton Transactions

Link: [{"URL"=>"http://pubs.rsc.org/en/content/articlepdf/2021/DT/D1DT01216A", "content-type"=>"unspecified", "content-version"=>"vor", "intended-application"=>"similarity-checking"}]

URL: http://dx.doi.org/10.1039/d1dt01216a

Reactions of a bis(boryl) tin complex towards carbon dioxide proceed via insertion into the Sn–B bond(s), with subsequent B–O reductive elimination leading to the net diboration of CO2.

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