Title: Heterotrimetallic Carbon Dioxide Copolymerization and Switchable Catalysts: Sodium is the Key to High Activity and Unusual Selectivity

Authors (2): A. Plajer, C. K. Williams

Themes: Circular Economy (2021)

DOI: 10.1002/anie.202101180

Citations: 51

Pub type: journal-article

Publisher: Wiley

Issue: 24

License: [{"start"=>{"date-parts"=>[[2021, 5, 10]], "date-time"=>"2021-05-10T00:00:00Z", "timestamp"=>1620604800000}, "content-version"=>"vor", "delay-in-days"=>0, "URL"=>"http://creativecommons.org/licenses/by/4.0/"}, {"start"=>{"date-parts"=>[[2021, 5, 10]], "date-time"=>"2021-05-10T00:00:00Z", "timestamp"=>1620604800000}, "content-version"=>"tdm", "delay-in-days"=>0, "URL"=>"http://doi.wiley.com/10.1002/tdm_license_1.1"}]

Publication date(s): 2021/06/07 (print) 2021/05/10 (online)

Pages: 13372-13379

Volume: 60 Issue: 24

Journal: Angewandte Chemie International Edition

Link: [{"URL"=>"https://onlinelibrary.wiley.com/doi/pdf/10.1002/anie.202101180", "content-type"=>"application/pdf", "content-version"=>"vor", "intended-application"=>"text-mining"}, {"URL"=>"https://onlinelibrary.wiley.com/doi/full-xml/10.1002/anie.202101180", "content-type"=>"application/xml", "content-version"=>"vor", "intended-application"=>"text-mining"}, {"URL"=>"https://onlinelibrary.wiley.com/doi/pdf/10.1002/anie.202101180", "content-type"=>"unspecified", "content-version"=>"vor", "intended-application"=>"similarity-checking"}]

URL: http://dx.doi.org/10.1002/anie.202101180

A dizinc-sodium catalyst has been synthesized which allows precise control of CO2 incorporation within poly(carbonates), -esters, and -ethers. The catalyst selectively switches between three distinct...

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anie202101180-sup-0001-misc_information.pdf Supl. data for Heterotrimetallic Carbon Dioxide Copolymerization and Swi... 2021


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