Title: Reversible C−H Activation, Facile C−B/B−H Metathesis and Apparent Hydroboration Catalysis by a Dimethylxanthene-Based Frustrated Lewis Pair

Authors (7): P. Vasko, I. A. Zulkifly, M. ÁN. Fuentes, Z. Mo, J. Hicks, P. C. J. .Kamer, S. Aldridge

Themes: Design (2018)

DOI: 10.1002/chem.201801871

Citations: 27

Pub type: article-journal

Publisher: Wiley

Issue: 41

License: [{"URL"=>"http://doi.wiley.com/10.1002/tdm_license_1.1", "start"=>{"date-parts"=>[[2018, 6, 27]], "date-time"=>"2018-06-27T00:00:00Z", "timestamp"=>1530057600000}, "delay-in-days"=>0, "content-version"=>"tdm"}, {"URL"=>"http://onlinelibrary.wiley.com/termsAndConditions#vor", "start"=>{"date-parts"=>[[2018, 6, 27]], "date-time"=>"2018-06-27T00:00:00Z", "timestamp"=>1530057600000}, "delay-in-days"=>0, "content-version"=>"vor"}]

Publication date(s): 2018/07/20 (print) 2018/06/27 (online)

Pages: 10531-10540

Volume: 24 Issue: 41

Journal: Chemistry - A European Journal

Link: [{"URL"=>"https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fchem.201801871", "content-type"=>"application/pdf", "content-version"=>"vor", "intended-application"=>"text-mining"}, {"URL"=>"http://onlinelibrary.wiley.com/wol1/doi/10.1002/chem.201801871/fullpdf", "content-type"=>"unspecified", "content-version"=>"vor", "intended-application"=>"similarity-checking"}]

URL: http://dx.doi.org/10.1002/chem.201801871

A dimethylxanthene-based FLP can effect reversible cleavage of the C−H bond in PhCCH, and can also react with B−H bonds, such as those in HBpin and HBcat via a B−C/B−H exchange. The latter reactivity...

Name Description Publised
CCDC 1827965: Experimental Crystal Structure Determination Related Article: Petra Vasko, Ili A. Zulkifly, M. Ã\x81ngeles Fuentes,... 2018
CCDC 1827966: Experimental Crystal Structure Determination Related Article: Petra Vasko, Ili A. Zulkifly, M. Ã\x81ngeles Fuentes,... 2018
CCDC 1827967: Experimental Crystal Structure Determination Related Article: Petra Vasko, Ili A. Zulkifly, M. Ã\x81ngeles Fuentes,... 2018
CCDC 1827968: Experimental Crystal Structure Determination Related Article: Petra Vasko, Ili A. Zulkifly, M. Ã\x81ngeles Fuentes,... 2018
CCDC 1827962: Experimental Crystal Structure Determination Related Article: Petra Vasko, Ili A. Zulkifly, M. Ã\x81ngeles Fuentes,... 2018
CCDC 1827963: Experimental Crystal Structure Determination Related Article: Petra Vasko, Ili A. Zulkifly, M. Ã\x81ngeles Fuentes,... 2018
CCDC 1827964: Experimental Crystal Structure Determination Related Article: Petra Vasko, Ili A. Zulkifly, M. Ã\x81ngeles Fuentes,... 2018
Supporting InformationReversible CH Activation, Facile CB/BH Metathesis andApparent Hydroboration Catalysis by a Dimethylxanthene-BasedFrustrated Lewis Pair Supl.... 2018


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