Title: Methanol loading dependent methoxylation in zeolite H-ZSM-5

Authors (4): S. K. Matam, S. A. F. .Nastase, A. J. Logsdail, C. R. A. .Catlow

Themes: Core (2020), Featured (2020)

DOI: 10.1039/d0sc01924k

Citations: 24

Pub type: article-journal

Publisher: Royal Society of Chemistry (RSC)

Issue: 26

License: {"URL"=>"http://creativecommons.org/licenses/by/3.0/", "start"=>{"date-parts"=>[[2020, 6, 17]], "date-time"=>"2020-06-17T00:00:00Z", "timestamp"=>1592352000000}, "delay-in-days"=>168, "content-version"=>"vor"}

Publication date(s): 2020/07/08 (print) 2020 (online)

Pages: 6805-6814

Volume: 11 Issue: 26

Journal: Chemical Science

Link: {"URL"=>"http://pubs.rsc.org/en/content/articlepdf/2020/SC/D0SC01924K", "content-type"=>"unspecified", "content-version"=>"vor", "intended-application"=>"similarity-checking"}

URL: http://dx.doi.org/10.1039/d0sc01924k

Room temperature methoxylation is methanol loading dependent: the higher the methanol loading, the faster the methoxylation. Methanol load of ≥2 leads to methoxylation while no methoxylation is observed with ≤1 molecule per Brønsted acidic site.

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