Cyclic ether and anhydride ring opening copolymerisation delivering new ABB sequences in poly(ester-<i>alt</i>-ethers)
Cyclic ether and anhydride ring opening copolymerisation delivering new ABB sequences in poly(ester-alt-ethers)
Authors (3): R. W. F. Kerr, A. R. Craze, C. K. Williams
Themes: Circular Economy
DOI: 10.1039/d4sc02051k
Citations: 10
Pub type: journal-article
Pub year: 2024

Publisher: Royal Society of Chemistry (RSC)

Issue: 29

License: [{"start"=>{"date-parts"=>[[2024, 6, 27]], "date-time"=>"2024-06-27T00:00:00Z", "timestamp"=>1719446400000}, "content-version"=>"vor", "delay-in-days"=>178, "URL"=>"http://creativecommons.org/licenses/by/3.0/"}]

Publication date(s): 2024/08/07 (print) 2024/06/27 (online)

Pages: 11617-11625

Volume: 15 Issue: {"issue"=>"29", "published-print"=>{"date-parts"=>[[2024, 7, 24]]}}

Journal: Chemical Science

Link: [{"URL"=>"http://pubs.rsc.org/en/content/articlepdf/2024/SC/D4SC02051K", "content-type"=>"unspecified", "content-version"=>"vor", "intended-application"=>"similarity-checking"}]

URL:

The synthesis of poly(ester-alt-ethers) is achieved by controlled ring-opening copolymerizations of commercial anhydrides and epoxides using a Zr(iv) catalyst. The catalysis shows unusual ABB monomer sequence selectivity and polymer properties depend upon both the monomers and the sequence.


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